THIS FILE IS IN COMMA-SEPARATED-VALUE FORMAT
Molecular Interactions in Crystal Structures with Z’ > 1,,,,
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"Robin Taylor, Jason C. Cole and Colin R. Groom, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK",,,,
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SUPPORTING INFORMATION,,,,
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All motifs in noncentrosymmetric structures whose %Z'>1 is statistically significant at the 99% confidence level,,,,
"Format differs slightly from main paper: opening and trailing curly arrows in motif strings are replaced by ""…""; triple bonds are represented by ""#""",,,,
shr = strong H-bonded ring; whr = weak H-bonded ring; st = stacking interaction (all types); ar_st = stacking (with major aromatic ring overlap),,,,
,,,,
motif,nstructures,%Z'>1,class,
...H-O-C=O...H-O-C=O...,211,75,shr, 
...H-N-C=N...H-N-C=N...,60,72,shr, 
...H-N-C=O...H-N-C=O...,381,71,shr, 
...H-N-C=S...H-N-C=S...,73,70,shr, 
...H-N-S=O...H-N-S=O...,52,63,shr, 
...H-Csp3-Csp3-Csp3-N-C=O...H-Csp3-Csp3-Csp3-N-C=O...,52,60, ,
...H-C~C-C=O...H-C~C-C=O...,94,60,whr,
...H-Csp3-N-M...H-Csp3-N-M...,68,59,st,
...C=N-Csp3...Csp2...,55,58, st,
...Csp2-C~C~C~C...Csp2-C~C~C~C...,129,57,st + ar_st,
...H-C~C-S=O...H-C~C-S=O...,106,57,whr,
...Csp2-C~C~C...C~C~C~C-Csp2...,63,56,st + ar_st,
...Csp2-C~C~C...Csp2-C~C~C~C...,115,55,st + ar_st,
...C~C-N...C~C-N...,116,54,st,
...Csp3-Csp3-C~C~C...H-Csp3-Csp3-C~C~C~C...,50,54, ,
...H-C~C-O...H-C~C-O...,144,53,whr,
...H-Csp3-Csp3-Csp3-Csp3-O-H...O-Csp3-Csp3-Csp3-Csp3-H...,79,53, ,
...Csp2-C~C~C~C...C~C~C...,98,53,st + ar_st,
...C~C-N=O...C~C~C~C...,66,53,st + ar_st,
...C~C~C~C...C~N...,53,53,st,
...H-N-Csp3-C=O...H-N-Csp3-C=O...,154,52,shr, 
...Csp2-O-Csp3-H...Csp2-O-Csp3-H...,148,51,st,
...H-Csp3-Csp2-N-Csp3-C=O...H-N-Csp3-C=O...,53,51, ,
...C~C~C...H-Csp3-N-M...,63,51,st,
...Csp2-N-Csp2...Csp2-N-Csp2...,87,51,st,
...Br-C~C-H...Br-C~C-H...,62,50, ,
...Csp2-C~C~C...Csp2-C~C~C...,194,50,st + ar_st,
...Csp2-C~C~C...C~C~C~C~C...,50,50,st + ar_st,
...C~C-Csp3-Csp3-Csp3-H...C~C~C-Csp3-Csp3-Csp3-H...,52,50, ,
...C~C~C~C-Csp3-H...H-Csp3-C~C-H...,56,50, ,
(Csp2)(N)(O=)C...C(=O)(Csp2)(N),91,49,st,
...Csp2-C~C~C~C...C~C~C~C~C...,65,49,st + ar_st,
...C~C~C~C-O-Csp3-H...C~C~C~C-O-Csp3-H...,61,49,st,
...H-C~C-N=O...H-C~C-N=O...,104,49,whr,
...C~C-H...C~C~C~C-Csp3-Csp3-C~C~C...,52,48, ,
...C~C~C-N...C~C~C-N...,71,48,st + ar_st,
...C~C~C-Csp3-Csp3-Csp3-H...C~C~C-Csp3-Csp3-Csp3-H...,69,48, ,
...H-C~C-Csp2-O...H-C~C-H...,57,47, ,
(Csp2)(H)(N=)C...C(=N)(Csp2)(H),72,47,st,
...C=O...H-N-Csp3-Csp2...,53,47, ,
...H-O...H-O...,53,47, ,
...H-Csp3-Csp3-N-C=O...H-Csp3-N-C=O...,68,47,whr,
...C~C~C-C~C-H...C~C~C-C~C-H...,66,47, ,
...Csp2-C~C~C~C...C~C~C~C...,133,47,st + ar_st,
...Csp2-N-Csp2...Csp3-Csp3-H...,69,46, ,
...Csp2-C~C...Csp2-C~C~C...,93,46,st + ar_st,
(C=)(Csp3)(H)C...C(=C)(Csp3)(H),97,45,st,
...Cl-M-N-H...Cl-M-N-H...,75,45,shr,
...H-Csp3-N-C=O...H-Csp3-N-C=O…,181,45,whr,
...C=O...N-Csp2...,106,45,st,
...Csp2-O...H-Csp3-O-C~C-H...,73,45,,
...N=O...N=O...,91,45,st,
...C~C~N...C~C~N...,67,45,st,
...C~C~C~C...C~C~C~N...,83,45,st + ar_st,
...Csp2-N-Csp2...Csp2-N...,108,44,st,
...H-Csp3-Csp3-Csp3-Csp3-O...H-O-Csp3-Csp3-H...,79,44, ,
(Csp3)(C~)(C~)C...C(O)(~C)(~C),113,44,st,
...Csp2-O-Csp3-H...O-Csp2...,77,44,,
...Csp2-N...N-Csp2...,118,44,st,
(C~)(C~)(N)C...C(N)(~C)(~C),198,44,st,
...C~C~C~C-Csp3-H...C~C~C~C-Csp3-H...,132,44,,
...Csp3-C~C-H...H-Csp3-C~C-H...,82,44,,
...H-Csp3-Csp3-N-Csp2-C~C-H...O...,89,44,,
...C~C~C~C-Csp3-Csp3-H...C~C~C~C-Csp3-Csp3-H...,87,44,,
...Csp2-Csp2...Csp2-C~C...,310,44,st,
...Csp2-Csp3-H...C~C~C-Csp3-H...,85,44,,
...Csp2-N...Csp2-N...,223,43,st,
...Csp3-C~C~C...H-Csp3-C~C~C...,115,43,,
...Csp2-C~C...C~C~C-Csp2...,76,43,st + ar_st,
...Csp2-N=O...C~C~C...,79,43,st,
...C=N-Csp3-Csp3-H...C~C...,86,43,,
...Csp2-H...O=S-N-Csp3-H...,84,43,,
...Br-C~C...H...,89,43,,
...C~C~C-Csp3-H...C~C~C~C-Csp3-H...,231,42,,
...H-Csp3-Csp3-C~C-H...H-Csp3-Csp3-C~C-H...,135,42,,
...C~C~C-Csp3-C~C~C...C~C~C-H...,93,42,,
...Csp2-C~C...C~C-Csp2...,136,42,st,
...Csp2-C~C...Csp2-C~C...,360,42,st,
...H-Csp3-N...H-Csp3-N…,101,42,whr,
...Csp2-C~C~C...C~C~C~C...,483,41,st + ar_st,
(Csp2)(C~)(C~)C...C(Csp2)(~C)(~C),372,41,st,
...H-Csp3-Csp3-N-C=O...H-N-Csp3-Csp3-H...,116,41, ,
...C=C-Csp2...C=C-Csp2...,225,41,st,
...C~C-Csp3-H...H-Csp3-C~C~C...,110,41,,
...Csp3-C~C~C...C~C~C~C...,128,41,st,
...C#O...M-Csp...,121,40,,
...C=O...C=O...,183,40,st,
...C~C~C~C...C~C~C~C...,581,40,st + ar_st,
(C~)(C~)(O)C...C(O)(~C)(~C),220,40,st,
...Csp3-Csp3-C~C...H-Csp3-Csp3-C~C~C...,140,40,,
...C~C~C-Csp3-Csp3-H...C~C~C~C-Csp3-Csp3-H...,178,40,,
...Csp2-N-Csp3-H...Csp2-N-Csp3-H...,118,40,,
...H-Csp3-Csp3-C=O...H-Csp3-Csp3-C=O...,294,39,whr,
...C~C-O-Csp3-H...C~C-O-Csp3-H...,189,39,,
...H-Csp3-C~C-H...H-Csp3-C~C-H...,210,39,,
...C~C~C-Csp3-H...C~C~C-Csp3-H...,437,39,,
...Csp2-Csp2...Csp2-O...,169,38,st,
...Csp2-Csp3-Csp3-H...Csp2-Csp3-Csp3-H...,255,38,,
(Csp3)(H)O...O(Csp3)(H),271,38,,
...H-C~C-Csp2-O...H...,233,38,,
...C~C~C-O-Csp3-H...C~C~C-O-Csp3-H...,181,38,,
...C~C~C-O-Csp3-H...C~C~C...,168,38,st,
...C~C~C~C...C~C~C~C~C...,226,38,st + ar_st,
...H-Csp3-Csp3-Csp3-O-H...O-Csp3-Csp3-Csp3-H...,216,38, ,
...C~C~C~C~C...C~C~C~C~C...,216,38,st + ar_st,
...C=N-N...H...,209,37,,
...C=C-Csp2...Csp2-Csp2...,239,37,st,
(Csp2)(H)(N)N...H(Csp2),233,37,,
...Csp2-Csp2...Csp2-Csp2...,542,37,st,
...C~C~C...C~C~C~C...,1332,37,st + ar_st,
...C~C-Csp3-Csp3-H...C~C~C-Csp3-Csp3-H...,329,37,,
...C~C~C-Csp3-Csp3-H...C~C~C-Csp3-Csp3-H...,290,36,,
...C~C-N...C~C~C~C...,249,36,st + ar_st,
...Csp2-Csp3-Csp3-H...C~C-Csp3-Csp3-H...,280,36,,
...C~C-Csp3-H...C~C-Csp3-H...,697,36,,
...C~C-Csp3-H...C~C~C-Csp3-H...,503,36,,
(O)H...H(O),308,35,,
...C=O...C~C...,353,35,st,
...C~C~C-Csp3-H...C~C~C~C...,348,35,,
(Csp2)(C~)(C~)C...C(O)(~C)(~C),296,35,st,
...C~C...C~C~C~C...,2083,35,st,
...C=C...Csp2-Csp2...,363,34,st,
...Csp2-Csp3-H...C~C-Csp3-H...,461,34,,
...H-Csp3-O...H-Csp3-O...,652,34,whr,
...C~C-Csp3-Csp3-H...C~C-Csp3-Csp3-H...,394,34,,
...Csp2-Csp3-H...Csp2-Csp3-H...,577,34,,
...Csp2-C~C~C...C~C~C...,591,34,st + ar_st,
...Csp2-C~C...C~C~C~C...,563,33,st + ar_st,
...C=C-N...H...,449,33,,
...C~C~C...C~C~C...,3102,33,st,
...Csp2...C~C~C...,1063,32,,
...Csp2-C~C...C~C~C...,1501,31,st,
...Csp2-C~C...C~C...,1693,31,st,
...Csp2-Csp2...Csp2...,2157,30,st,
...C~C...C~C~C...,4127,30,st,